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Type: Artigo de periódico
Title: Thermal Behavior Of α-ba(fes2)2 And Agfes2: Quasi-unidimensional And 3d Network Compounds Prepared From Ion-exchange On The Same Precursor
Author: Galembeck A.
Alves O.L.
Abstract: Thermal behavior of AgFeS2 and α-Ba(FeS2)2 were studied under air atmosphere. Decomposition products of AgFeS2 are Ag2S, FeS2 (pyrite form), Ag2SO4, α-Fe2O3 and metallic silver α-Ba(FeS2)2 decomposes to pyrite, α-Fe2O3 and BaSO4. We propose that metallic sulfide formation on the initial step of the decomposition of these compounds is related to the packing of the metallic ions with sulfur and, hence, with metal-sulfur distances in the original material. Morphological information about AgFeS2 and α-Ba(FeS2)2 are presented for the first time.
Editor: Kluwer Academic Publishers, Dordrecht, Netherlands
Rights: fechado
Identifier DOI: 10.1023/A:1004646326407
Date Issue: 1999
Appears in Collections:Unicamp - Artigos e Outros Documentos

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