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Type: Artigo de periódico
Title: Oxidation Of Hydrocarbons With Peroxides Catalyzed By Chromium(iii) And Iron(iii) Incorporated In Sapo-37 Framework
Author: Spinace E.V.
Schuchardt U.
Cardoso D.
Abstract: SAPO-37 containing structural chromium(III) and iron(III) ions were tested as catalysts in liquid phase oxidation of benzene and cyclohexane, using hydrogen peroxide and tert-butylhydroperoxide as oxidants. Only chromium(III) is active as oxidation catalyst. In spite of the SAPO-37 framework stability under the reaction conditions, leaching of small quantities of chromium occurs and the observed catalytic reaction is mainly due to the chromium ions in solution. © 1999 Elsevier Science B.V. All rights reserved.
Rights: fechado
Identifier DOI: 
Date Issue: 1999
Appears in Collections:Unicamp - Artigos e Outros Documentos

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