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|Type:||Artigo de periódico|
|Title:||Oxidation Of Hydrocarbons With Peroxides Catalyzed By Chromium(iii) And Iron(iii) Incorporated In Sapo-37 Framework|
|Abstract:||SAPO-37 containing structural chromium(III) and iron(III) ions were tested as catalysts in liquid phase oxidation of benzene and cyclohexane, using hydrogen peroxide and tert-butylhydroperoxide as oxidants. Only chromium(III) is active as oxidation catalyst. In spite of the SAPO-37 framework stability under the reaction conditions, leaching of small quantities of chromium occurs and the observed catalytic reaction is mainly due to the chromium ions in solution. © 1999 Elsevier Science B.V. All rights reserved.|
|Appears in Collections:||Unicamp - Artigos e Outros Documentos|
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