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Type: Artigo de periódico
Title: Enantioselective Synthesis Of A-hydroxysilanes By Bioreduction Of Aroyltrimcthylsilanes
Author: Patrocinio A.F.
Correa Jr. I.R.
Moran P.J.S.
Abstract: Aromatic acylsilanes [Ar-CO-SiMe3; Ar = C6H5,4-ClC6H4, 2-, 3- and 4-OMeC6H4, 3,4-(OMe)2C6H3 and 3,4-OCH2OC6H3] were reduced by baker's yeast to optically active a-silyl alcohols in 20-70% yield and 43-88% ee. Comments are made on the influence of silicon in this bioreduction reaction. © The Royal Society of Chemistry 1999.
Rights: fechado
Identifier DOI: 
Date Issue: 1999
Appears in Collections:Unicamp - Artigos e Outros Documentos

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