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Type: Artigo de periódico
Title: Preparation And Mössbauer Studies Of Iron-mercury Mixed Isocyanide-carbonyl Complexes
Author: Morigaki M.K.
Machado L.C.
Da Silva E.M.
Larica C.
Armando Filho B.
Dias G.H.M.
Abstract: The reactions of [Fe(t-BuNC)3(CO)2] with HgX2 (X = Cl, Br or I) give two different types of iron-mercury halide complex, depending on the molar ratio of reactants used. An equimolar ratio of the reactants produces the neutral adducts [Fe(t-BuNC)3(CO)2(HgX2)], whereas two equivalents of HgX2 generate the electrolytes [Fe(t-BuNC)3(CO)2(HgX)]HgX3. The Mössbauer, i.r. data, and conductivity measurements of these complexes are presented and discussed in terms of their chemical structures and bonding.
Rights: fechado
Identifier DOI: 
Date Issue: 1999
Appears in Collections:Unicamp - Artigos e Outros Documentos

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