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|Type:||Artigo de periódico|
|Title:||Differential Oxidation Of Endocyclic Enecarbamates. Synthesis Of Cyclic β-hydroxy-α-amino Acids|
|Abstract:||The differential oxidation of five and six-membered endocyclic enecarbamates was investigated employing m-CPBA, DMD, as well as enantioselectivc protocols such as the Kochi-Jacobsen-Katsuki's epoxidation and the Sharpless dihydroxylation. By this strategy the syntheses of β- hydroxyprolines and β-hydroxypipecolic acids were accomplished, X-Ray crystallographic analysis of the trans-β-hydroxypipecolic acid was instrumental to solve structural assignment conflicts.|
|Appears in Collections:||Unicamp - Artigos e Outros Documentos|
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