Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/100435
Type: Artigo de periódico
Title: On 1,4-diastereoselectivity In The Chiral Allylsilane Addition To Chiral α-substituted Aldehydes
Author: Dias L.C.
Giacomini R.
Abstract: Chiral allyisilane 2 reacted with chiral α-substituted aldehydes to afford the corresponding 1,4-syn-products with good diastereoseletivities. The best selectivities are observe when the reactions are carried out by transmetallation of allylsilane using Tin (IV) chloride in CH2Cl2, at - 78°C, before addition of the aldehydes.
Editor: 
Rights: fechado
Identifier DOI: 10.1016/S0040-4039(98)01066-1
Address: http://www.scopus.com/inward/record.url?eid=2-s2.0-0032560775&partnerID=40&md5=1b012d2ae820960a17c5153dcf6f2e24
Date Issue: 1998
Appears in Collections:Unicamp - Artigos e Outros Documentos

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