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Type: Artigo de periódico
Title: On 1,4-diastereoselectivity In The Chiral Allylsilane Addition To Chiral α-substituted Aldehydes
Author: Dias L.C.
Giacomini R.
Abstract: Chiral allyisilane 2 reacted with chiral α-substituted aldehydes to afford the corresponding 1,4-syn-products with good diastereoseletivities. The best selectivities are observe when the reactions are carried out by transmetallation of allylsilane using Tin (IV) chloride in CH2Cl2, at - 78°C, before addition of the aldehydes.
Rights: fechado
Identifier DOI: 10.1016/S0040-4039(98)01066-1
Date Issue: 1998
Appears in Collections:Unicamp - Artigos e Outros Documentos

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