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|Type:||Artigo de periódico|
|Title:||Direct Selective Oxidation Of Benzene To Phenol Using Molecular Oxygen In The Presence Of Palladium And Heteropolyacids|
|Abstract:||The use of heteropolyacids as a reoxidant for palladium in the direct oxidation of benzene to phenol with molecular oxygen was studied as a function of the variables involved. It was shown that the oxidation system is very effective even if a molar ratio of HOAc:H2O of 1:2 is used. After 4 h at 130°C the benzene conversion is 15% and the selectivity for phenol is above 70%. The quantity of palladium acetate can be drastically reduced allowing turnover numbers as high as 800.|
|Appears in Collections:||Unicamp - Artigos e Outros Documentos|
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