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Type: Artigo de periódico
Title: Shvo's catalyst in chemoenzymatic dynamic kinetic resolution of amines - inner or outer sphere mechanism
Author: Vaz, BG
Milagre, CDF
Eberlin, MN
Milagre, HMS
Abstract: Evidence is provided for the inner-sphere mechanism with actual metal coordination of the racemic amine in the crucial hydrogen transfer step promoted by Shvo's catalyst of the chemoenzymatic dynamic kinetic resolution (DKR) of amines. Key intermediates involved in this H-transfer step were intercepted and continuously monitored by electrospray ionization mass spectrometry (ESI-MS) and characterized by their dissociation chemistries via ESI-MS/MS.
Country: Inglaterra
Editor: Royal Soc Chemistry
Citation: Organic & Biomolecular Chemistry. Royal Soc Chemistry, v. 11, n. 39, n. 6695, n. 6698, 2013.
Rights: embargo
Identifier DOI: 10.1039/c3ob41318g
Date Issue: 2013
Appears in Collections:Unicamp - Artigos e Outros Documentos

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