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Type: Artigo de periódico
Title: 1,2-octanediol deracemization by stereoinversion using whole cells
Author: Chen, LS
Mantovani, SM
de Oliveira, LG
Duarte, MCT
Marsaioli, AJ
Abstract: This paper describes the stereoinversion of (R)-1,2-octanediol promoted by Aspergillus niger CCT 1435 and Candida albicans CCT 0776 from Brazilian collections. Racemic 1,2-octanediol can be converted into (S)-1,2-octanediol with 70% isolated yield and 99% ee in 10 h using C albicans. This is one of the best results in the literature and on-going experiments indicate that the reaction rate can be further accelerated. (C) 2007 Elsevier B.V. All rights reserved.
Subject: deracemization
Country: Holanda
Editor: Elsevier Science Bv
Citation: Journal Of Molecular Catalysis B-enzymatic. Elsevier Science Bv, v. 54, n. 41671, n. 50, n. 54, 2008.
Rights: fechado
Identifier DOI: 10.1016/j.molcatb.2007.11.022
Date Issue: 2008
Appears in Collections:Unicamp - Artigos e Outros Documentos

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